Mestrado em Engenharia Ambiental

URI Permanente para esta coleção

http://repositorio.ufes.br/handle/10/17612

Nível: Mestrado Acadêmico
Ano de início:
Conceito atual na CAPES:
Ato normativo:
Periodicidade de seleção:
Área(s) de concentração:
Url do curso:

Navegar

Navegando Mestrado em Engenharia Ambiental por Assunto "Adsorção competitiva"

Agora exibindo 1 - 1 de 1
  • Nenhuma Miniatura disponível
    Item
    Avaliação da remoção de 2,4-d e atrazina por carvão ativado : um estudo da competição em adsorção
    (Universidade Federal do Espírito Santo, 2024-09-24) Rafalscky, Lays; Britto, Gilberto Maia; https://orcid.org/; http://lattes.cnpq.br/; Co-orientador2; https://orcid.org/; http://lattes.cnpq.br/; Co-orientador3; https://orcid.org/; http://lattes.cnpq.br/; Co-orientador4; ID do co-orientador4; Lattes do co-orientador4; Coelho, Edumar Ramos Cabral; https://orcid.org/; http://lattes.cnpq.br/; Orientador2; https://orcid.org/; http://lattes.cnpq.br/; https://orcid.org/; http://lattes.cnpq.br/; Gonçalves, Ricardo Franci; https://orcid.org/; http://lattes.cnpq.br/; Capelo Neto, José; https://orcid.org/; http://lattes.cnpq.br/; 3º membro da banca; https://orcid.org/; http://lattes.cnpq.br/; 4º membro da banca; http://lattes.cnpq.br/; 5º membro da banca; https://orcid.org/; http://lattes.cnpq.br/; 6º membro da banca; https://orcid.org/; http://lattes.cnpq.br/; 7º membro da banca; https://orcid.org/; http://lattes.cnpq.br/
    The presence of pesticides in drinking water is concerning due to the toxicity and bioaccumulation potential of these compounds. In this context, adsorption by activated carbon has gained attention as an alternative for removing microcontaminants in water treatment. Several variables can influence adsorption, one of the most notable being the competition among multiple contaminants for the adsorption sites on the activated carbon. This work conducted a systematic review guided by the PRISMA guideline to establish the state of the art on competitive adsorption. The review data were obtained using the keywords “Competitive adsorption,” “Powder Carbon” “Activated Carbon,” and “Water Treatment,” covering the years 2000 to 2023. The selected articles were categorized into: competition between metals, competition between metals and organic compounds, and competition between organic compounds. The review results contributed to understanding the existing research gaps in the field. In the laboratory tests, the activated carbon was characterized by several techniques to identify functional groups, porosity, moisture content, and ash content, among other parameters. Then, the isolated and competitive removal of two highly commercialized herbicides in Brazil, atrazine and 2,4-D, was tested in the state of Espírito Santo, with adsorption evaluated in terms of kinetics and isotherms. The Freundlich model showed the best fit for both pesticides in isolated systems. The adsorption of 2,4-D was significantly affected by the presence of atrazine due to its hydrophilic nature in the study's pH range (6-7). A computational study was conducted to suggest potential mechanisms, and the results indicated a predominance of π-π interactions, which is consistent with findings in the literature. The results suggest that the commercial carbon from Bahia Carbon is a strong candidate for removing 2,4-D and atrazine in isolated systems, but the presence of atrazine may significantly affect the removal of 2,4-D